I have not found any specific details relating to hospital ships, usually those merchant ships hired for use as transports or store ships were chartered, usually by renting the cargo space onboard, so a ship would be hired to take stores from port A to port B "at a rate of £x per ton, for such quantity as shall be put aboard". The crew etc. would be provided by the owners and there would not be a naval presence onboard.
One would presume that if planned for use as a hospital, then a Surgeon and supporting team would have been provided (by the Sick & Hurt Board?)
If used as a troop transport then the agreement would be to take men from A to B at £x per head - usually the navy would provide beds & bedding, but the merchant owners would have to provide "..water, good new provisions, bowles, platters, cans, spoons, coals, candles and utensils for cooking and dressing of the victuals.."
As an aside, this evidently led to overcrowding, or at least in did in the 1776-82 period "...men were packed in like herring; a tall man could not stand upright between decks nor sit up straight in his berth..."
Where hired ships were intended for use as a warship, then naval officers would usually be assigned, I believe
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